First, it's possible for the red capt to pick the blue capt
[22:05:52] [%white[choc]lastpickmousepadcha] .teams
[22:05:52] [@GUBER] »» Red Team: white[choc]lastpickmousepadcha Steel ««
[22:05:52] [@GUBER] »» Blue Team: Steel white[choc]lastpickmousepadcha ««
Second, looks like it's possible to pick the players who join late in a pug (jyb was the 11th player here I think)
[22:24:21] [@GUBER] »» GU.iCTF.5v5 [11/10] 1) risus`[brbnocap] 2) Shiva`300toomuch[brbsmokenocapfuckPAC] 3) DamagedPhone 4) JD 5) biz 6) Turok 7) ApOkaL1pS[nocapt] 10) n0mer ««
[22:24:23] [+SanGrooF] .pick jyb
[22:24:24] [@GUBER] »» Red Team: SanGrooF jyb ««